{"id":1039,"date":"2023-12-27T13:54:47","date_gmt":"2023-12-27T05:54:47","guid":{"rendered":"https:\/\/www.battery-material.com\/?p=1039"},"modified":"2023-12-27T13:59:20","modified_gmt":"2023-12-27T05:59:20","slug":"graphite-or-silicon-based-lithium-ion-battery-anode-material-prospects","status":"publish","type":"post","link":"https:\/\/www.battery-material.com\/pt\/graphite-or-silicon-based-lithium-ion-battery-anode-material-prospects\/","title":{"rendered":"Perspectivas de material an\u00f3dico de bateria de \u00edon de l\u00edtio \u00e0 base de grafite ou sil\u00edcio"},"content":{"rendered":"
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Ap\u00f3s anos de desenvolvimento, a densidade de energia das baterias de \u00edons de l\u00edtio melhorou bastante. As estat\u00edsticas mostram que a densidade de energia das baterias de \u00edon-l\u00edtio aumentou tr\u00eas vezes entre 1991 e 2015, com uma GAGR (taxa anual de crescimento composto) de cerca de 3%. No entanto, do ponto de vista do desenvolvimento tecnol\u00f3gico real, a actual taxa de crescimento da densidade energ\u00e9tica das baterias de i\u00f5es de l\u00edtio abrandou significativamente e os produtos convencionais est\u00e3o pr\u00f3ximos do limite m\u00e1ximo da densidade energ\u00e9tica. Somente rompendo as amarras dos materiais e das tecnologias poderemos alcan\u00e7ar avan\u00e7os cont\u00ednuos na densidade de energia das baterias. Durante muito tempo, os materiais cat\u00f3dicos foram considerados uma restri\u00e7\u00e3o na melhoria do desempenho da bateria devido \u00e0 sua baixa capacidade espec\u00edfica. Ap\u00f3s uma grande quantidade de investimento em pesquisa, materiais cat\u00f3dicos como \u00f3xido em camadas (\u00f3xido de l\u00edtio-cobalto), fosfato de ferro-l\u00edtio, fosfato de mangan\u00eas-ferro-l\u00edtio, materiais tern\u00e1rios e materiais tern\u00e1rios com alto teor de n\u00edquel foram desenvolvidos um ap\u00f3s o outro. A capacidade espec\u00edfica dos materiais cat\u00f3dicos aumentou de 120mAh para 120mAh. \/g (mAh\/g) \u00e9 aumentado gradualmente para 210mAh\/g. Hoje em dia, com o desenvolvimento da tecnologia de baterias aproximando-se do seu limite e a melhoria da capacidade dos materiais cat\u00f3dicos encontrando gargalos, o desenvolvimento e aplica\u00e7\u00e3o de materiais an\u00f3dicos com maior capacidade espec\u00edfica tornou-se a chave para romper o teto de densidade de energia das baterias de \u00edon-l\u00edtio.<\/p>

Quando uma bateria de \u00edons de l\u00edtio \u00e9 carregada, os \u00edons de l\u00edtio gerados pelo eletrodo positivo s\u00e3o incorporados no eletrodo negativo atrav\u00e9s do eletr\u00f3lito. Quanto mais \u00edons de l\u00edtio incorporados no eletrodo negativo, maior ser\u00e1 a capacidade de carga. Os materiais an\u00f3dicos afetam principalmente a primeira efici\u00eancia coulombiana, densidade de energia, desempenho do ciclo, etc. das baterias de \u00edon-l\u00edtio e s\u00e3o uma das mat\u00e9rias-primas mais importantes para baterias de \u00edon-l\u00edtio. Os materiais an\u00f3dicos atualmente usados em baterias comerciais de \u00edons de l\u00edtio incluem principalmente: materiais de carbono semelhantes a grafite, principalmente grafite artificial e grafite natural; materiais de carbono desordenados, incluindo carbono duro e carbono macio; materiais de titanato de l\u00edtio; materiais \u00e0 base de sil\u00edcio, incluindo principalmente materiais comp\u00f3sitos de \u00f3xido de sil\u00edcio revestidos de carbono, materiais comp\u00f3sitos de nano sil\u00edcio e carbono, etc. O r\u00e1pido desenvolvimento de novos ve\u00edculos de energia e ind\u00fastrias de armazenamento de energia impulsionou o crescimento explosivo de baterias de \u00edon-l\u00edtio.<\/p>

O \u00e2nodo de sil\u00edcio tem um potencial moderado de inser\u00e7\u00e3o de l\u00edtio (~0,4V vs. Li+\/Li). N\u00e3o h\u00e1 perigo oculto de precipita\u00e7\u00e3o de l\u00edtio durante o processo de carregamento, o que melhora o desempenho de seguran\u00e7a das baterias de \u00edons de l\u00edtio. \u00c9 mais promissor substituir o grafite como a pr\u00f3xima gera\u00e7\u00e3o de baterias de \u00edons de l\u00edtio de alto desempenho. material de eletrodo negativo. No entanto, a litia\u00e7\u00e3o do sil\u00edcio tem as desvantagens inerentes de grande expans\u00e3o de volume (> 300%), baixa condutividade e baixo coeficiente de difus\u00e3o de \u00edons de l\u00edtio, fazendo com que os materiais an\u00f3dicos \u00e0 base de sil\u00edcio ainda n\u00e3o alcancem aplica\u00e7\u00e3o no mercado em larga escala.<\/p>

Atualmente, a ind\u00fastria de materiais para \u00e2nodos de baterias de l\u00edtio est\u00e1 em um ponto cr\u00edtico em sua transforma\u00e7\u00e3o. As empresas l\u00edderes t\u00eam vantagens \u00f3bvias em termos de capital e tecnol\u00f3gicas, e as barreiras \u00e0 entrada para os retardat\u00e1rios est\u00e3o a aumentar constantemente. As empresas petroqu\u00edmicas podem combinar suas vantagens no campo de mat\u00e9rias-primas de coque agulhado para grafite artificial e entrar rapidamente no setor, adquirindo empresas de fabrica\u00e7\u00e3o de grafitiza\u00e7\u00e3o e estabelecendo alian\u00e7as estrat\u00e9gicas com empresas l\u00edderes do setor e institui\u00e7\u00f5es de P&D para alcan\u00e7ar a fabrica\u00e7\u00e3o integrada de grafite artificial e obter melhores resultados. Muitas oportunidades para o desenvolvimento sustent\u00e1vel. Em termos de materiais an\u00f3dicos de sil\u00edcio-carbono, a promo\u00e7\u00e3o e transforma\u00e7\u00e3o tecnol\u00f3gica devem ser aceleradas, os crit\u00e9rios de avalia\u00e7\u00e3o para os parceiros de coopera\u00e7\u00e3o devem ser flexibilizados, um sistema progressivo de taxas de licenciamento de tecnologia deve ser explorado, o limiar para a coopera\u00e7\u00e3o deve ser reduzido e as aplica\u00e7\u00f5es comerciais devem ser promovidas. .<\/p>\t\t\t\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t\t<\/div>\n\t\t\t\t<\/div>\n\t\t\t\t<\/div>","protected":false},"excerpt":{"rendered":"

Ap\u00f3s anos de desenvolvimento, a densidade energ\u00e9tica das baterias de \u00edons de l\u00edtio foi significativamente aprimorada. Estat\u00edsticas mostram que a densidade energ\u00e9tica das baterias de \u00edons de l\u00edtio triplicou entre 1991 e 2015, com uma GAGR (taxa de crescimento anual composta) de cerca de 3%. No entanto, da perspectiva do desenvolvimento tecnol\u00f3gico atual, a taxa de crescimento atual das baterias de \u00edons de l\u00edtio [\u2026]<\/p>","protected":false},"author":1,"featured_media":1040,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"site-sidebar-layout":"default","site-content-layout":"","ast-site-content-layout":"default","site-content-style":"default","site-sidebar-style":"default","ast-global-header-display":"","ast-banner-title-visibility":"","ast-main-header-display":"","ast-hfb-above-header-display":"","ast-hfb-below-header-display":"","ast-hfb-mobile-header-display":"","site-post-title":"","ast-breadcrumbs-content":"","ast-featured-img":"","footer-sml-layout":"","ast-disable-related-posts":"","theme-transparent-header-meta":"","adv-header-id-meta":"","stick-header-meta":"","header-above-stick-meta":"","header-main-stick-meta":"","header-below-stick-meta":"","astra-migrate-meta-layouts":"set","ast-page-background-enabled":"default","ast-page-background-meta":{"desktop":{"background-color":"var(--ast-global-color-4)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"ast-content-background-meta":{"desktop":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"tablet":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""},"mobile":{"background-color":"var(--ast-global-color-5)","background-image":"","background-repeat":"repeat","background-position":"center center","background-size":"auto","background-attachment":"scroll","background-type":"","background-media":"","overlay-type":"","overlay-color":"","overlay-opacity":"","overlay-gradient":""}},"footnotes":""},"categories":[1],"tags":[],"class_list":["post-1039","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-graphite-anode-material-processing"],"yoast_head":"\nGraphite or silicon-based, lithium-ion battery anode material prospects - Battery material powder-making equipment from China<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.battery-material.com\/pt\/graphite-or-silicon-based-lithium-ion-battery-anode-material-prospects\/\" \/>\n<meta property=\"og:locale\" content=\"pt_PT\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Graphite or silicon-based, lithium-ion battery anode material prospects - Battery material powder-making equipment from China\" \/>\n<meta property=\"og:description\" content=\"After years of development, the energy density of lithium-ion batteries has been greatly improved. 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